Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2019

Ключевые слова: Gold(III), molecular spectroscopy, Organic disulfides, Platinum(II), redox reactions

Аннотация: The interaction of Pt(II) and Au(III) with disulfides (l-cystine, cystamine, dl-homocystine and 3,3′-dithiodipropionic acid) in hydrochloric acid aqueous solutions was studied. In the case of Pt(II), the oxidative addition reaction leads to formation of the Pt(IV) thiol complex. In the case of Au(III) disulfide, binding causes a reduction to Au(0) and oxidation of the disulfide to sulfonic acid. Cyclic voltammetry and different spectroscopic methods were used to study the process. The pattern of influence of the metallic properties for d8 ions in the direction of the reaction was found.

Журнал: Journal of Coordination Chemistry

Выпуск журнала: Т. 72, № 17

Номера страниц: 2916-2930

ISSN журнала: 00958972

Издатель: Gordon and Breach Science Publishers

• Petrov A.I. (Institute of Chemistry and Chemical Technology SB RAS,Federal Research Center “Krasnoyarsk Science Center SB RAS”)
• Novikova G.V. (Institute of Non-Ferrous Metals and Materials Science,Siberian Federal University)
• Demina A.V. (Institute of Non-Ferrous Metals and Materials Science,Siberian Federal University)
• Ivanenko T.Y. (Institute of Non-Ferrous Metals and Materials Science,Siberian Federal University)
• Goleva E.S. (Institute of Non-Ferrous Metals and Materials Science,Siberian Federal University)

• Ядро РИНЦ (eLIBRARY.RU)