Unraveling the Near-Unity Narrow-Band Green Emission in Zero-Dimensional Mn2+-Based Metal Halides: A Case Study of (C10H16N)2Zn1-xMnxBr4 Solid Solutions | Научно-инновационный портал СФУ

Unraveling the Near-Unity Narrow-Band Green Emission in Zero-Dimensional Mn2+-Based Metal Halides: A Case Study of (C10H16N)2Zn1-xMnxBr4 Solid Solutions

Тип публикации: статья из журнала

Год издания: 2020

Идентификатор DOI: 10.1021/acs.jpclett.0c01933

Аннотация: Zero-dimensional (0D) Mn2+-based metal halides are potential candidates as narrow-band green emitters, and thus it is critical to provide a structural understanding of the photophysical process. Herein, we propose that a sufficiently long Mn-Mn distance in 0D metal halides enables all Mn2+ centers to emit spontaneously, thereby leading to near-unity photoluminescence quantum yield. Taking lead-free (C10H16N)2Zn1-xMnxBr4 (x = 0-1) solid solution as an example, the Zn/Mn alloying inhibits the concentration quenching that is caused by the energy transfer of Mn2+. (C10H16N)2MnBr4 exhibits highly thermal stable luminescence even up to 150 °C with a narrow-band green emission at 518 nm and a full width at half maximum of 46 nm. The fabricated white light-emitting diode device shows a high luminous efficacy of 120 lm/W and a wide color gamut of 104% National Television System Committee standard, suggesting its potential for liquid crystal displays backlighting. These results provide a guidance for designing new narrow-band green emitters in Mn2+-based metal halides.

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Издание

Журнал: The journal of physical chemistry letters

Выпуск журнала: Vol. 11, Is. 15

Номера страниц: 5956-5962

ISSN журнала: 19487185

Авторы

  • Zhou G. (State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou, 510641, China, Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University, Linfen, 041004, China, Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology BeijingBeijing 100083, China)
  • Liu Z. (Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, 430074, China)
  • Huang J. (State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou, 510641, China)
  • Molokeev M.S. (Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation, Department of Physics, Far Eastern State Transport UniversityKhabarovsk 680021, Russian Federation)
  • Xiao Z. (Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, 430074, China)
  • Ma C. (Chongqing University of Posts and TelecommunicationsChongqing 400065, China)
  • Xia Z. (State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou, 510641, China, Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology BeijingBeijing 100083, China)

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