Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2016

Идентификатор DOI: 10.1134/S003602361606022X

Ключевые слова: Hydrogen bonds, Bismuth complexes, Mutual repulsion, Octahedral cation, Thiocarbonyl, Crystal structure

Аннотация: The structure of the bismuth(III) complex with N-ethylthiourea (Ettu) has been determined for the first time. We found that the crystal structure of [Bi(Ettu)(4)(ClO4)(2)]ClO4 is built of distorted octahedral cations [Bi(Ettu-S)(4)(ClO4)(2)]ClO4](+) and anions ClO (4) (-) . The deviation of one of the two independent Ettu molecules from the plane structure is explained by the mutual repulsion of the ligands and the formation features of hydrogen bonds. The C2H5(Ettu) group is in the cis position relative to the thiocarbonyl group.

Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Выпуск журнала: Vol. 61, Is. 6

Номера страниц: 704-707

ISSN журнала: 00360236

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

• Vasil'ev A.D. (Siberian Federal University)
• Golovnev N.N. (Siberian Federal University)
• Lesnikov M.K. (Siberian Federal University)

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