Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2016

Идентификатор DOI: 10.1134/S0020168516060029

Ключевые слова: high-temperature heat capacity, thermodynamic functions, Differential scanning calorimetry, Gadolinium, High temperature applications, Solid state reactions, Temperature, Tin, Enthalpy increments, Entropy changes, High temperature, Pyrochlore structures, Reduced Gibbs energies, Stannates, Temperature range, Specific heat

Аннотация: Gd2Sn2O7 gadolinium stannate with the pyrochlore structure has been prepared by solid-state reaction and its high-temperature heat capacity has been determined by differential scanning calorimetry in the temperature range 350-1020 K. The C (p) (T) data are shown to be well represented by the classic Maier-Kelley equation. The experimental C (p) (T) data have been used to evaluate the thermodynamic functions of gadolinium stannate: enthalpy increment HA degrees(T)-HA degrees(339 K), entropy change SA degrees(T)-SA degrees(339 K), and reduced Gibbs energy Dcurrency signA degrees(T).

Журнал: INORGANIC MATERIALS

Выпуск журнала: Vol. 52, Is. 6

Номера страниц: 584-586

ISSN журнала: 00201685

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

• Denisova L.T. (Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia)
• Irtyugo L.A. (Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia)
• Kargin Yu. F. (Russian Acad Sci, Baikov Inst Met & Mat Sci, Leninskii Pr 49, Moscow 119991, Russia)
• Beletskii V.V. (Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia)
• Denisov V.M. (Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia)

• Web of Science Core Collection
• Scopus (цитирований 3)
• РИНЦ (eLIBRARY.RU)