Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2009

Идентификатор DOI: 10.1007/s11172-009-0122-3

Ключевые слова: vinylidene complexes, heterometallic complexes, manganese, rhenium, palladium, platinum, IR and NMR spectroscopy, X-ray diffraction study

Аннотация: The reactions of Cp(CO)(2)Re=C=CHPh (2) with M(PPh(3))(4) (M = Pd, Pt) gave the mu-vinylidene complexes Cp(CO)(2)RePd(mu-C=CHPh)(PPh(3))(2) (3) and Cp(CO)(2)RePt(mu-C=CHPh)(PPh(3))(2) (1), respectively. The substitution of Ph(2)PCH(2)PPh(2) (dppm) for the PPh(3) ligands in 1 resulted in the formation of Cp(CO)RePt(mu-C(1)=C(2)HPh)(mu-CO)(dppm) (4). The structure of complex 4 has been determined by single-crystal X-ray diffraction analysis. The structural and spectroscopic characteristics of complexes 1, 3, and 4 were compared with the corresponding parameters of the manganese-containing analogs Cp(CO)(2)MnPd(mu-C=CHPh)(PPh(3))(2) (5), Cp(CO)(2)MnPt(mu-C=CHPh)(PPh(3))(2) (6) and Cp(CO)(2)MnPt(mu-C=CHPh)(dppm) (7).

Журнал: RUSSIAN CHEMICAL BULLETIN

Выпуск журнала: Vol. 58, Is. 5

Номера страниц: 955-963

ISSN журнала: 10665285

Место издания: NEW YORK

Издатель: SPRINGER

• Antonova A.B. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Chudin O.S. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Pavlenko N.I. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Sokolenko W.A. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Rubaylo A.I. (Siberian Federal University)
• Vasiliev A.D. (L. V. Kirensky Institute of Physics,Siberian Branch of the Russian Academy of Sciences Akademgorodok)
• Verpekin V.V. (Siberian Federal University)
• Semeikin O.V. (A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences)

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