Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2013

Идентификатор DOI: 10.1016/j.ica.2012.06.038

Ключевые слова: Rhenium, Platinum, Vinylidene complexes, Heterometallic complexes, Carbonyl complexes

Аннотация: Reaction of Cp(CO)(2)Re=C=CHPh (1) with Pt(PPh3)(4) and subsequent treatment of Cp(CO)(2)RePt (mu-C=CHPh)(PPh3)(2) (2) with diphosphines P-P = dppe, dppp afforded new complexes Cp(CO)(2)RePt (mu-C=CHPh)(P-P) (4, 5). The structures of Cp(CO)(2)RePt(mu-C=CHPh)(dppp) (5) and Cp(CO)(2)MnPt (mu-C=CHPh)(dppp) (10) have been determined by single crystal XRD. The influence of the nature of M = Re, Mn and L-2 = (PPh3)(2), dppm, dppe, dppp at the Pt atom on the structural, IR and H-1, C-13 and P-31 NMR spectroscopic characteristics of complexes Cp(CO)(2)MPt(mu-C=CHPh)(L-2) (2-5, 7-10) is considered. (C) 2012 Published by Elsevier B.V.

Журнал: INORGANICA CHIMICA ACTA

Выпуск журнала: Vol. 394

Номера страниц: 328-336

ISSN журнала: 00201693

Место издания: LAUSANNE

Издатель: ELSEVIER SCIENCE SA

• Antonova A.B. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Verpekin V.V. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Chudin O.S. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Pavlenko N.I. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Sokolenko W.A. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Rubaylo A.I. (Siberian Federal University)
• Vasiliev A.D. (Siberian Federal University)
• Semeikin O.V. (A.N. Nesmeyanov Institute of Organo-Element Compounds,Russian Academy of Sciences)

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