Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2018

Идентификатор DOI: 10.1016/j.moistruc.2018.03.020

Ключевые слова: Rhenium, Platinum, Vinylidene complexes, Heterometallic complexes, Electrochemistry

Аннотация: The novel heterobinuclear mu-vinylidene complex [Cp(CO)(2)Re(mu-C=CHPh)Pt(PPh3)(CO)%(1) was isolated from the reaction mixture of [Cp(CO)(2)Re(R-C=CHPh)Fe(CO)(4)%and Pt(PPh3)(4) for the first time. Alternative high-yield synthetic approaches to 1 were developed including the reactions of [Cp(CO)(2)Re(mu-C=CHPh) Pt(PPh3)(2)%(2) with Co-2(CO)(8) and Rh(acac)(CO)(2). The complex was characterized by IR and H-1, C-13 and P-31 NMR spectroscopy, a molecular structure of 1 was determined by X-ray diffraction analysis. The electrochemical behavior of the new complex was studied by cyclic voltammetry at platinum or glassed carbon electrodes and by dc polarography at a dropping mercury electrode. (C) 2018 Elsevier B.V. All rights reserved.

Журнал: JOURNAL OF MOLECULAR STRUCTURE

Выпуск журнала: Vol. 1163

Номера страниц: 308-315

ISSN журнала: 00222860

Место издания: AMSTERDAM

Издатель: ELSEVIER SCIENCE BV

• Verpekin Victor V. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Vasiliev Alexander D. (RAS, SB, Fed Res Ctr, Inst Phys,Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia; RAS, Fed Res Ctr, SB, Krasnoyarsk Sci Ctr, Akademgorodok 50, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia)
• Kondrasenko Alexander A. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Burmakina Galina V. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia)
• Chudin Oleg S. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Pavlenko Nina I. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Zimonin Dmitry V. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Rubaylo Anatoly I. (RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia; RAS, Fed Res Ctr, SB, Krasnoyarsk Sci Ctr, Akademgorodok 50, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia)

• Web of Science Core Collection