Тип публикации: статья из журнала
Год издания: 2020
Идентификатор DOI: 10.1039/c9tc06976c
Аннотация: Exotic perovskites significantly enrich materials for multiferroic and magnetoelectric applications. However, their design and synthesis is a challenge due to the mostly required recipe conditions at extremely high pressure. Herein, we presented the Ca2-xMnxMnTaO6 (0 ≤ x ≤ 1.0) solid solutions stabilized by chemical pressure assisted with intermediate physical pressure up to 7 GPa. The incorporation of Mn2+ into the A-site neither drives any cationic ordering nor modifies the orthorhombic Pbnm structure, namely written as (Ca1-x/2Mnx/2)(Mn1/2Ta1/2)O3 with disordered A and B site cationic arrangements. The increment of x is accompanied by a ferromagnetic to antiferromagnetic transition around x = 0.2, which is attributed to the double-exchange interactions between A-site Mn2+ and B-site Mn3+. Partial charge disproportionation of the B-site Mn3+ into Mn2+ and Mn4+ occurs for x above 0.8 samples as manifested by X-ray spectrum and magnetic behaviors. The coexistence of B-site Mn3+ (Jahn-Teller distortion ion) and B′-site Ta5+ (second-order Jahn-Teller distortion ion) could be energetically responsible for the absence of A-site columnar ordering as observed in other quadruple perovskites with half of the A-sites occupied by small transition-metal cations. These exceptional findings indicate that exotic perovskites can be successfully stabilized at chemical and intermediate physical pressure, and the presence of Jahn-Teller distortion cations at the same lattice should be avoided to enable cationic ordering. This journal is © The Royal Society of Chemistry.
Издание
Журнал: Journal of Materials Chemistry C
Выпуск журнала: Vol. 8, Is. 15
Номера страниц: 5082-5091
ISSN журнала: 20507534
Издатель: Royal Society of Chemistry
Персоны
- Ma Yalin (Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China)
- Molokeev Maxim S. (RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Krasnoyarsk 660041, Russia; Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia)
- Zhu Chuanhui (Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China)
- Zhao Shuang (Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China)
- Han Yifeng (Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China)
- Wu Meixia (Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China)
- Liu Sizhan (New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA)
- Tyson Trevor A. (New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA)
- Croft Mark (Rutgers State Univ, Dept Phys & Astron, 136 Frelinghuysen Rd, Piscataway, NJ 08854 USA)
- Li Man-Rong (Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China)
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