Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2012

Идентификатор DOI: 10.1134/S0036024412020070

Ключевые слова: bimetallic powders, gold-palladium, redox potential, Bimetallic particles, Hydrochloric acid solution, Nernst equation, Redox potentials, Gold, Hydrochloric acid, Redox reactions, Secondary batteries, Transmission electron microscopy, X ray diffraction analysis, Powders

Аннотация: The redox potential of fine-dispersed and compact bimetallic powders of the palladium-gold system in hydrochloric acid solutions of H2PdCl4 at a temperature of 60A degrees C was studied. It was found that the redox potential increases with gold enrichment of the solid solution in accordance with the Nernst equation. The effect of gold-palladium particle size on this redox potential is shown. The morphology, sizes, and composition of bimetallic particles are determined via transmission electron microscopy and X-ray diffraction analysis.

Журнал: RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A

Выпуск журнала: Vol. 86, Is. 3

Номера страниц: 484-488

ISSN журнала: 00360244

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

• Belousov O.V. (Institute of Chemistry and Chemical Technology,Russian Academy of Sciences,Siberian Branch)
• Borisov R.V. (Institute of Chemistry and Chemical Technology,Russian Academy of Sciences,Siberian Branch)
• Parfenov V.A. (Institute of Chemistry and Chemical Technology,Russian Academy of Sciences,Siberian Branch)
• Dorokhova L.I. (Institute of Chemistry and Chemical Technology,Russian Academy of Sciences,Siberian Branch)
• Zharkov S.M. (Siberian Federal University)

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