Тип публикации: статья из журнала
Год издания: 2001
Идентификатор DOI: 10.1149/1.1386642
Аннотация: The Seebeck coefficient of a cell with lead electrodes and electrolyte of molten lead chloride and alkali chloride is investigated experimentally and theoretically for mole fractions of PbCl2 between l and 0.3 in alkali chlorides. An equation is derived from irreversible thermodynamics linking the transported entropy of lead ion to the chemical potential of the polarized lead at the surface. The path across the cell is taken to be adiabatic in this derivation. Experimental results indicate that the transported entropy of lead ions depends on the radius of the alkali ion. (C) 2001 The Electrochemical Society.
Издание
Журнал: JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Выпуск журнала: Vol. 148, Is. 9
Номера страниц: 364-371
ISSN журнала: 00134651
Место издания: PENNINGTON
Издатель: ELECTROCHEMICAL SOC INC
Персоны
- Blinov V. (Krasnoyarsk State Acad Nonferrous Met & Gold, Krasnoyarsk 660025, Russia)
- Kjelstrup S. (Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan; Norwegian Univ. Sci. Technol., T., 7491 Trondheim, Norway)
- Bedeaux D. (Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan; Leiden Institute of Chemistry, Leiden University, Leiden, Netherlands)
- Sharivker V. (Reactive Energy LLC, Sci. Applic. Intl. Corporation, Ottawa, Ont. KIA OH3, Canada)
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