Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2013

Идентификатор DOI: 10.1134/S0036023613110235

Ключевые слова: Alternating layers, Crystal and molecular structure, Formamidines, Framework structures, Inversion center, Space Groups, Hydrogen bonds, Positive ions, Crystal structure

Аннотация: The crystal and molecular structure of bis(alpha,alpha'-dithio-bis(formamidinium)) bis(mu(2)-chloro)hexachlorodimercurate(II) C4H16Hg2Cl8N8S4 (I), where alpha,alpha'-dithio-bis(formamidine) is C2H6N4S2, was solved. Crystals are monoclinic, a = 8.6417(6) , b = 14.648(1) , c = 10.2111(8) , beta = 104.949(1)A degrees, V = 1248.8(2) (3), space group P2(1)/n, Z = 4. The crystal structure is built of HgCl (4) (2-) ions linked via inversion centers into [Hg2Cl8](4-) pairs and C2H8N4S (2) (2+) cations. [Hg2Cl8](4-) anions and C2H8N4S (2) (2+) cations form alternating layers linked by N-HaEuro broken vertical bar Cl hydrogen bonds into a framework structure.

Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Выпуск журнала: Vol. 58, Is. 11

Номера страниц: 1298-1301

ISSN журнала: 00360236

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

• Vasiliev A.D. (Siberian Federal University)
• Golovnev N.N. (Siberian Federal University)

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