Сибирский федеральный университет

Тип публикации: доклад, тезисы доклада, статья из сборника материалов конференций

Конференция: International Multidisciplinary Scientific Geoconference; Albena, BULGARIA; Albena, BULGARIA

Год издания: 2013

Идентификатор DOI: 10.5593/SGEM2013/BA1.V1/S01.007

Ключевые слова: cations, isomorphism, crystal structure, point defects, pyrrhotite, Sations, Basis of calculation, Crystalline structure, Electrical conductivity, Electronic configuration, Isomorphic substitution, Atoms, Exhibitions, Iron ores, Positive ions, Vacancies, Crystal impurities

Аннотация: Based on analysis of the electronic configuration of the impurity in minerals have a crystalline structure such as NiAs (eg, pyrrhotite), a correlation of electrical conductivity, density impurity atoms, and the density cation vacancies. The density cation vacancies increases with the total density of the impurity atoms increases, thus reducing the conductivity of the crystal decrease. Shown that the nature of these phenomena - decrease in the concentration of electrons in the conduction zone as a result of the capture of an electron vacancy impurity atoms. On the basis of calculations of the density impurity investigated the properties of anionic impurity atoms and analyzed the mechanism of isomorphic substitution of sulfur ions in the structure of pyrrhotite.

Журнал: International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM

Выпуск журнала: Vol. 1

Номера страниц: 47-54

ISSN журнала: 13142704

• Onufrienok V. (Siberian Federal University)
• Sazonov A. (Siberian Federal University)

• Web of Science Core Collection
• Scopus
• Ядро РИНЦ (eLIBRARY.RU)