Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2013

Идентификатор DOI: 10.1134/S1070328413020097

Ключевые слова: Crystallographic data, Hydrogen atoms, Hydrogen bond networks, IR and Raman spectroscopy, Space Groups, Sulfur atoms, Atoms, Complex networks, Hydrogen bonds, Raman spectroscopy, Single crystals, X ray diffraction, Thioureas

Аннотация: The complex[Bi-2(Tu)(6)(ClO4)(4)](ClO4)(2) (I) (Tu is thiourea) was synthesized and studied by X-ray diffraction. The crystallographic data of I are: a = 14.205(1) , b = 13.083(1) , c = 22.078(2) , beta = 96.182(1)A degrees, V = 4079.1(7) (3), space group C2/c, Z = 4. The molecule is located on a twofold axis and consists of the binuclear cation [Bi-2(Tu)(6)(ClO4)(4)](2+) and two outer-sphere anions Cl (4) (-) . The Bi-S bond lengths are 2.61-2.62 . For each terminal and bridging ClO (4) (-) ion, one Bi-O distance varies from 2.744 to 3.048 3.269 structure contains a hydrogen bond network involving all hydrogen atoms. The IR and Raman spectroscopy data confirm the thiourea coordination by the sulfur atom.

Журнал: RUSSIAN JOURNAL OF COORDINATION CHEMISTRY

Выпуск журнала: Vol. 39, Is. 2

Номера страниц: 161-164

ISSN журнала: 10703284

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

• Vasiliev A.D. (Siberian Federal University)
• Golovnev N.N. (Siberian Federal University)

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