Non-stoichiometry in Ca2Al2SiO7 enabling mixed-valent europium toward ratiometric temperature sensing : научное издание | Научно-инновационный портал СФУ

Non-stoichiometry in Ca2Al2SiO7 enabling mixed-valent europium toward ratiometric temperature sensing : научное издание

Тип публикации: статья из журнала

Год издания: 2019

Идентификатор DOI: 10.1007/s40843-019-1202-x

Ключевые слова: temperature sensing, phosphor, Eu2+/Eu3+, intervalence charge transfer

Аннотация: Eu2+/Eu3+ mixed-valence couple co-doped material holds great potential for ratiometric temperature sensing owing to its different electronic configurations and electron-lattice interaction. Here, the correlation of nonstoichiometry in chemical composition, phase structures and luminescence propertis of Ca2Al2Si1-xO7:Eu is discussed, and controlled Eu2+/Eu3+ valence and tunable emission appear with decreasing Si content. It is found that the 2Ca(2+) + Si4+ Eu2+ + Eu3+ + Al3+ cosubstitution accounts for the structural stability and charge balance mechanism. Benefiting from the diverse thermal dependent emission behaviors of Eu2+ and Eu3+, Ca2Al2Si1-xO7:Eu thermometer exhibits excellent temperature sensing performances with the maximum absolute and relative sensitivity being 0.024 K-1 (at 303 K) and 2.46% K-1 (at 443 K) and good signal discriminability. We propose that the emission quenching of Eu2+ is ascribed to 5d electrons depopulation through Eu2+/Eu3+ intervalence charge transfer state, while the quenching of Eu3+ comes from multi phonon relaxation. Our work demonstrates the potential of Ca2Al2Si1-xO7:Eu for noncontact optical thermometry, and also highlights mixed valence europium containing com pounds toward temperature sensing.

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Издание

Журнал: SCIENCE CHINA-MATERIALS

ISSN журнала: 20958226

Место издания: BEIJING

Издатель: SCIENCE PRESS

Авторы

  • Hu Tao (South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China)
  • Gao Yan (Wuyi Univ, Sch Appl Phys & Mat, Jiangmen 529020, Peoples R China)
  • Molokeev Maxim (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Krasnoyarsk 660041, Russia; Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, RussiaArticle)
  • Xia Zhiguo (South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China)
  • Zhang Qinyuan (South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China)

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