Composition and Structure of Block-Type Ferrospheres Isolated from Calcium-Rich Power Plant Ash

Тип публикации: статья из журнала

Год издания: 2018

Идентификатор DOI: 10.1134/S0020168518020012

Ключевые слова: ferrospheres with a blocky structure, formation paths

Аннотация: Polished sections of individual ferrospheres 30 to 40 mu m in size, with single-block and blocky structures and a variable glass phase content, have been studied using a scanning electron microscope equipped with an energy dispersive X-ray spectrometer system. The results demonstrate that the single-block globules consist of sintered magnetite crystallites containing Al2O3, MgO, and CaO as impurities and are formed from the pyrite of the initial coal. Characteristically, the ferrospheres with a variable glass phase content differ in the composition of local areas on polished sections of the globules, which attests to inhomogeneity of the melt droplets they formed from. We have identified groups of globules whose overall composition, as well as the composition of their local areas, meet general equations for the interrelation between the concentrations of their components: SiO2 = f(FeO) and SiO2 = f(Al2O3). Comparison of the coefficients of the SiO2 = f(Al2O3) dependence for the globules with the silicate modulus (SiO2/Al2O3) of the aluminosilicate mineral components of the coal indicates that the formation of this type of globules involves pyrite-anorthite or pyrite-albite associates containing quartz impurities. The composition of the spinel ferrite in the globules produced with the participation of anorthite comprises FeO, Al2O3, MgO, and CaO in concentrations of 85-96, 1.7-10, 0.1-1.8, and 0.3-2.8 wt %, respectively. In the albite-based globules, the respective concentrations are 81-92, 0.7-5.9, 1.0-5.7, and 2.2-5.6 wt %. The crystallite size and shape are determined by the size of the local melt areas where the total concentration of spinel-forming oxides exceeds 85 wt %.

Ссылки на полный текст

Издание

Журнал: INORGANIC MATERIALS

Выпуск журнала: Vol. 54, Is. 2

Номера страниц: 187-194

ISSN журнала: 00201685

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

Авторы

  • Anshits N.N. (SB RAS, Inst Chem & Chem Technol, Fed Res Ctr Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
  • Fedorchak M.A. (SB RAS, Inst Chem & Chem Technol, Fed Res Ctr Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
  • Zhizhaev A.M. (SB RAS, Inst Chem & Chem Technol, Fed Res Ctr Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
  • Sharonova O.M. (SB RAS, Inst Chem & Chem Technol, Fed Res Ctr Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
  • Anshits A.G. (SB RAS, Inst Chem & Chem Technol, Fed Res Ctr Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia)

Вхождение в базы данных

Информация о публикациях загружается с сайта службы поддержки публикационной активности СФУ. Сообщите, если заметили неточности.

Вы можете отметить интересные фрагменты текста, которые будут доступны по уникальной ссылке в адресной строке браузера.