The modulated structure and frequency upconversion properties of CaLa2(MoO4)(4):Ho3+/Yb3+ phosphors prepared by microwave synthesis | Научно-инновационный портал СФУ

The modulated structure and frequency upconversion properties of CaLa2(MoO4)(4):Ho3+/Yb3+ phosphors prepared by microwave synthesis

Тип публикации: статья из журнала

Год издания: 2015

Идентификатор DOI: 10.1039/c5cp03054d

Аннотация: CaLa2-x(MoO4)(4):Ho3+/Yb3+ phosphors with the doping concentrations of Ho3+ and Yb3+ (x = Ho3+ + Yb3+, Ho3+ = 0.05; Yb3+ = 0.35, 0.40, 0.45 and 0.50) have been successfully synthesized by the microwave sol-gel method. The modulated and averaged crystal structures of CaLa2-x(MoO4)(4):Ho3+/Yb3+ molybdates have been found by the Rietveld method, and the upconversion photoluminescence properties have been investigated. The synthesized particles, being formed after the heat-treatment at 900 degrees C for 16 h, showed a highly crystallized state. Under the excitation at 980 nm, CaLa2-x(MoO4)(4):Ho3+/Yb3+ particles exhibited strong 545 and 655 nm emission bands in the green and red regions. When the Yb3+ : Ho3+ ratios are 9 : 1 and 10 : 1, the UC intensity of CaLa1.5(MoO4)(4):Yb-0.45/Ho-0.05 and CaLa1.45(MoO4)(4):Yb-0.50/Ho-0.05 particles is the highest for different bands. The CIE coordinates calculated for CaLa2-x(MoO4)(4):Ho3+/Yb3+ phosphors are related to the yellow color field. The Raman spectrum of undoped CaLa2(MoO4)(4) has revealed about 13 narrow lines. The strongest band observed at 906 cm(-1) was assigned to the nu(1) symmetric stretching vibration of MoO4 tetrahedra. The spectra of the samples doped with Ho and Yb, as obtained under the 514.5 nm excitation, were dominated by Ho3+ luminescence over the wavenumber range of >700 cm(-1) preventing the recording of the Raman spectra.

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Издание

Журнал: PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Выпуск журнала: Vol. 17, Is. 29

Номера страниц: 19278-19287

ISSN журнала: 14639076

Место издания: CAMBRIDGE

Издатель: ROYAL SOC CHEMISTRY

Авторы

  • Lim Chang Sung (Hanseo Univ, Dept Adv Mat Sci & Engn, Seosan 356706, South Korea)
  • Aleksandrovsky Aleksandr (SB RAS, Kirensky Inst Phys, Lab Coherent Opt, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia)
  • Molokeev Maxim (SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia; Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia)
  • Oreshonkov Aleksandr (Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia; SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk 660036, Russia)
  • Atuchin Victor (SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia; Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia)

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