Сибирский федеральный университет

Тип публикации: статья из журнала

Год издания: 2016

Идентификатор DOI: 10.1080/00150193.2016.1214525

Ключевые слова: Phase transition, fluorides, oxyfluorides, thermal properties, barocaloric effect, Chemical compounds, Entropy, Fluorine compounds, Magnetocaloric effects, Order disorder transitions, Phase diagrams, Phase transitions, Thermodynamic properties, Barocaloric effects, Chemical pressures, Effective tool, Order disorder phase transitions, Pressure phase, Transition entropies, High pressure effects

Аннотация: Using the data about the temperature - pressure phase diagram and the phase transition entropy at ambient and high pressure, intensive and extensive barocaloric effects were analyzed in the region of single and successive order-disorder phase transitions in fluorides and oxyfluorides with the elpasolites-cryolite structure. It was found that hydrostatic as well as chemical pressure are the effective tools to change the entropy of compounds with disordered ionic groups or atoms in structure and to realize the significant intensive and extensive barocaloric effects comparable with the values of baro- and magnetocaloric effects, characteristic for materials, considered as promising solid refrigerants.

Журнал: FERROELECTRICS

Выпуск журнала: Vol. 500, Is. 1

Номера страниц: 153-163

ISSN журнала: 00150193

Место издания: ABINGDON

Издатель: TAYLOR & FRANCIS LTD

• Flerov I.N. (Siberian Federal University)
• Gorev M.V. (Siberian Federal University)
• Bogdanov E.V. (Krasnoyarsk State Agrarian University)
• Laptash N.M. (Institute of Chemistry,Far Eastern Department of RAS)

• Web of Science Core Collection
• Scopus
• Ядро РИНЦ (eLIBRARY.RU)