Тип публикации: статья из журнала
Год издания: 2018
Идентификатор DOI: 10.3390/s18072141
Ключевые слова: Ammonia, Chemiresistive sensors, DFT calculations, Metal phthalocyanines, Thin films
Аннотация: In this work, the sensor response of MPcFx (M = Cu, Co, Zn; x = 0, 4, 16) films toward gaseous NH3 (10-50 ppm) was studied by a chemiresistive method and compared to that of unsubstituted MPc films to reveal the effects of central metals and F-substituents on the sensing properties. A combination of atomic force microscopy and X-ray diffraction techniques have been used to elucidate the structural features of thin MPcFx films deposited by organic molecular beam deposition. It has been shown that the sensor response of MPcF4 films to ammonia is noticeably higher than that of MPc films, which is in good correlation with the values of binding energy between the metal phthalocyanine and NH3 molecules, as calculated by the density functional theory (DFT) method. At the same time, in contrast to the DFT calculations, MPcF16 demonstrated the lesser sensor response compared with MPcF4, which appeared to be connected with the different structure and morphology of their films. The ZnPcF4 films were shown to exhibit a sensitivity to ammonia up to concentrations as low as 0.1 ppm, and can be used for the selective detection of ammonia in the presence of some reducing gases and volatile organic compounds. Moreover, the ZnPcF4 films can be used for the detection of NH3 in the gas mixture simulating exhaled air (N2 76%, O2 16%, H2O 5%, and CO2 3%). © 2018 by the authors.
Издание
Журнал: Sensors (Switzerland)
Выпуск журнала: Vol. 18, Is. 7
Номера страниц: 2142
ISSN журнала: 14248220
Издатель: MDPI AG
Персоны
- Klyamer D. (Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk, Russian Federation)
- Sukhikh A. (Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk, Russian Federation, Department of Natural Sciences, Novosibirsk State University, 2 Pirogov street, Novosibirsk, Russian Federation)
- Gromilov S. (Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk, Russian Federation, Department of Natural Sciences, Novosibirsk State University, 2 Pirogov street, Novosibirsk, Russian Federation)
- Krasnov P. (Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation, Reshetnev Siberian State University of Science and Technology, 82 Mira prospect, Krasnoyarsk, Russian Federation)
- Basova T. (Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk, Russian Federation, Department of Natural Sciences, Novosibirsk State University, 2 Pirogov street, Novosibirsk, Russian Federation)
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