Structural transformations and phenomenological description of the formation of phase states in elpasolites Cs2RbDyF6 and Rb2KB'F-6 (B' = Ho, Dy, Tb) | Научно-инновационный портал СФУ

Structural transformations and phenomenological description of the formation of phase states in elpasolites Cs2RbDyF6 and Rb2KB'F-6 (B' = Ho, Dy, Tb)

Тип публикации: статья из журнала (материалы конференций, опубликованные в журналах)

Конференция: All Russia Conference on Physics of Ferroelectrics (VKS-20); Krasnoyarsk, RUSSIA; Krasnoyarsk, RUSSIA

Год издания: 2015

Идентификатор DOI: 10.1134/S1063783415030282

Аннотация: The structures of the cubic and monoclinic phases of an Rb2KHoF6 crystal from a series of elpasolites Rb2KB'F-6 (B' = Ho, Dy, Tb), which undergoes a trigger phase transition, have been investigated using X-ray powder diffraction. The critical and noncritical displacements of atoms in the Rb2KHoF6 structure have been determined from the group-theoretical analysis of the complete condensate of order parameters. It has been reliably established that a change in the symmetry due to the phase transition in this crystal can be represented in the form . A phenomenological analysis of the conditions responsible for the formation of phase states upon the phase transitions in elpasolites Cs2RbDyF6 and Rb2KB'F-6 (B' = Ho, Dy, Tb) has been carried out. Taking into account the structural data and using the phenomenological theory, it has been found that the main factor determining the formation of phase states in these and related crystals is the instability of the elpasolite structure with respect to rotational distortions of two types. It has been shown that an important role in the formation of a sequence of structural transformations in these crystals is played by the interaction of rotational order parameters and displacements of the cation from the center of a cuboctahedral hole.

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Издание

Журнал: PHYSICS OF THE SOLID STATE

Выпуск журнала: Vol. 57, Is. 3

Номера страниц: 491-498

ISSN журнала: 10637834

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

Авторы

  • Safonov I.N. (Siberian Federal University)
  • Misyul' S.V. (Siberian Federal University)
  • Molokeev M.S. (Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences)
  • Ivliev M.P. (Research Institute of Physics, Southern Federal University)

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