Тип публикации: статья из журнала
Год издания: 2010
Идентификатор DOI: 10.3103/S1067821210060039
Ключевые слова: electrolytic obtaining of aluminum, dry gas purification, secondary alumina, fluorinated alumina, determination of the fluorine content, adsorption model, weight loss, Adsorption, Air purification, Aluminum, Chemisorption, Desorption, Fluorine compounds, Gas fuel purification, Heating, Fluorine, aluminum oxide, electrolyte, moisture, temperature effect
Аннотация: The losses of weight and F-containing compounds by secondary alumina at various temperatures which can be reached in a bunker of automated feeding by alumina (AFA)-i.e., to 80, 100, 200, 300, and 400A degrees C-are evaluated. The fluorine content in alumina after being held at a specified temperature was determined by the photocolorimetric method. Upon the heating of secondary alumina, noticeable losses of weight and fluorine were observed in it starting from t > 80A degrees C, which is associated with the removal of the latter with physically adsorbed moisture. However, the larger part of fluorine remains in secondary alumina even at t = 400A degrees C, because it consists of solid fluorides and chemisorbed particles. The desorption of fluorine from alumina even at relatively low temperatures (starting from 80A degrees C) means that constructive and technological measures are necessary to decrease them in AFA bunkers.
Журнал: RUSSIAN JOURNAL OF NON-FERROUS METALS
Выпуск журнала: Vol. 51, Is. 6
Номера страниц: 447-450
ISSN журнала: 10678212
Место издания: NEW YORK
Издатель: ALLERTON PRESS INC
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